May 16, 2010

Civil Service Exam Syllabus for IAS Main Exam - Chemistry Paper-I


Civil Service Exam Syllabus for IAS Main Exam - Chemistry Paper-I
1. Atomic Structure:
Heisenberg's uncertainty principle, Schrodinger wave equation (time independent); Interpretation of wave function, particle in one-dimensional box, quantum numbers, hydrogen atom wave functions; Shapes of s, p and d orbitals.
2. Chemical Bonding:
Ionic bond, characteristics of ionic compounds, lattice energy, Born-Haber cycle; covalent bond and its general characteristics, polarities of bonds in molecules and their dipole moments; Valence bond theory, concept of resonance and resonance energy; Molecular orbital theory (LCAO method); bonding in H2+, H2, He2+ to Ne2, NO, CO, HF, and CN–; Comparison of valence bond and molecular orbital theories, bond order, bond strength and bond length.
3. Solid State:
Crystal systems; Designation of crystal faces, lattice structures and unit cell; Bragg's law; X-ray diffraction by crystals; Close packing, radius ratio rules, calculation of some limiting radius ratio values; Structures of NaCl, ZnS, CsCl and CaF2; Stoichiometric and nonstoichiometric defects, impurity defects, semi-conductors.
4. The Gaseous State and Transport Phenomenon:
Equation of state for real gases, intermolecular interactions and critical phenomena and liquefaction of gases, Maxwell's distribution of speeds, intermolecular collisions, collisions on the wall and effusion; Thermal conductivity and viscosity of ideal gases.
5. Liquid State:
Kelvin equation; Surface tension and surface energy, wetting and contact angle, interfacial tension and capillary action.
6. Thermodynamics:
Work, heat and internal energy; first law of thermodynamics.
Second law of thermodynamics; entropy as a state function, entropy changes in various processes, entropy–reversibility and irreversibility, Free energy functions; Thermodynamic equation of state; Maxwell relations; Temperature, volume and pressure dependence of U, H, A, G, Cp and Cv, α and β; J-T effect and inversion temperature; criteria for equilibrium, relation between equilibrium constant and thermodynamic quantities; Nernst heat theorem, introductory idea of third law of thermodynamics.
7. Phase Equilibria and Solutions:
Clausius-Clapeyron equation; phase diagram for a pure substance; phase equilibria in binary systems, partially miscible liquids–upper and lower critical solution temperatures; partial molar quantities, their significance and determination; excess thermodynamic functions and their determination.
8. Electrochemistry:
Debye-Huckel theory of strong electrolytes and Debye-Huckel limiting Law for various equilibrium and transport properties.
Galvanic cells, concentration cells; electrochemical series, measurement of e.m.f. of cells and its applications fuel cells and batteries.
Processes at electrodes; double layer at the interface; rate of charge transfer, current density; overpotential; electroanalytical techniques: Polarography, amperometry, ion selective electrodes and their uses.
9. Chemical Kinetics:
Differential and integral rate equations for zeroth, first, second and fractional order reactions; Rate equations involving reverse, parallel, consecutive and chain reactions; branching chain and explosions; effect of temperature and pressure on rate constant; Study of fast reactions by stop-flow and relaxation methods; Collisions and transition state theories.
10. Photochemistry:
Absorption of light; decay of excited state by different routes; photochemical reactions between hydrogen and halogens and their quantum yields.
11. Surface Phenomena and Catalysis:
Absorption from gases and solutions on solid adsorbents, Langmuir and B.E.T. adsorption isotherms; determination of surface area, characteristics and mechanism of reaction on heterogeneous catalysts.
12. Bio-inorganic Chemistry:
Metal ions in biological systems and their role in ion transport across the membranes (molecular mechanism), oxygen-uptake proteins, cytochromes and ferredoxins.
13. Coordination Compounds:
1. Bonding theories of metal complexes; Valence bond theory, crystal field theory and its modifications; applications of theories in the explanation of magnetism and electronic spectra of metal complexes.
2. Isomerism in coordination compounds; IUPAC nomenclature of coordination compounds; stereochemistry of complexes with 4 and 6 coordination numbers; chelate effect and polynuclear complexes; trans effect and its theories; kinetics of substitution reactions in square-planer complexes; thermodynamic and kinetic stability of complexes.
3. EAN rule, Synthesis structure and reactivity of metal carbonyls; carboxylate anions, carbonyl hydrides and metal nitrosyl compounds.
4. Complexes with aromatic systems, synthesis, structure and bonding in metal olefin complexes, alkyne complexes and cyclopentadienyl complexes; coordinative unsaturation, oxidative addition reactions, insertion reactions, fluxional molecules and their characterization; Compounds with metal-metal bonds and metal atom clusters.
14. Main Group Chemistry:
Boranes, borazines, phosphazenes and cyclic phosphazene, silicates and silicones, Interhalogen compounds; Sulphur – nitrogen compounds, noble gas compounds.
15. General Chemistry of ‘f’ Block Elements:
Lanthanides and actinides; separation, oxidation states, magnetic and spectral properties; lanthanide contraction.

Tags:Civil Services India,UPSC Exam India,IAS Results IAS Syllabus, UPSC Syllabus, Subjects for IAS Exam, Syllabus  UPSC Civil Service Syllabus Geography,UPSC Geography Syllabus for UPSC Civil Services Examination - Education in India, Courses & Studies Civil Service Exam Syllabus for IAS Main Exam 

FEEL USEFUL PLEASE GIVE +1

0 comments :

Post a Comment

Get Syllabus in your Mail

Labels

Accenture Admission Notice - 2010 Admission Notification Anna University Anna University Chennai Anna University Question Papers Anna University Trichy Apparel Technology and Management Aptitude Questions Arts and Science Colleges Biomedical Engineering C and CPP Ebooks Calicut University CBSE Question papers Civil Engineering Civil Service Exams Colleges in India Colleges Result Computer Science Engineering Core Jobs CS R2008 CSE CSIR NET EBooks Download ECE EEE EIE Electives Electrical and Electronics Engineering Electronics and communication Electronics and Instrumentation Engineering Engineering Engineering Colleges in Maharashtra Engineering Colleges in TamilNadu Engineering Admissions Engineering Colleges Engineering Colleges in Karnataka Engineering Jobs Engineering Syllabus Entrance Exam Dates Entrance Exam Results Entrance Examination Exam Time Table Experiencer First Year Syllabus Freshers Full Time Jobs Government jobs in india Hardware and Networking Jobs Hotel Management and Catering Technology IGNOU Information Technology INTEVIEW QUESTIONS IT Jobs JNTU Question Papers Jobs in Bangalore Jobs in Chennai Jobs in Coimbatore Jobs in Delhi Jobs in Hyderabad Jobs in India Jobs in Kerala Jobs in Noida Jobs in Tamilnadu Jobs in TATA Karnataka Educations Lab Manuals Mechanical Engineering Medical Colleges Placement Papers Plus 2 Preparation for exams Private Jobs in India Question Papers Question Papers Download Results Announcement Semester 1 Semester 2 Semester 3 Semester 4 Semester 5 Semester 6 Semester 7 Semester 8 Syllabus Syllabus Download Tamil Movie TCS Placement Papers Teaching Jobs TECH MAHINDRA Textile Technology Top colleges University Results UPSC VICEVESVARAYA TECHNOLOGICAL UNIVERSITY waec Walk-in Interview Web Designers

Followers

Archive

 

Privacy Policy
http://topengineeringcollegesintamilnadu.blogspot.com use third-party advertising companies to serve ads when you visit our website. These companies may use information (not including your name, address, email address, or telephone number) about your visits to this and other websites in order to provide advertisements about goods and services of interest to you. If you would like more information about this practice and to know your choices about not having this information used by these companies, click here.